N-Ethyl-N-phenyl-p-toluenesulfonamide

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N-Ethyl-N-phenyl-p-toluene­sulfonamide

In the title compound, C(15)H(17)NO(2)S, the aromatic rings are oriented at a dihedral angle of 32.8 (1)°. The ethyl group and phenyl ring on the N atom adopt a staggered conformation with respect to the O atoms.

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A rhodium-catalyzed ortho-cyanation of symmetrical azobenzenes is described employing N-cyano-N-phenyl-p-toluenesulfonamide as an environmentally friendly cyanide source. The present protocol allows the synthesis of various benzonitrile derivatives in moderate to good yields and tolerates many useful functional groups.

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N-Ethyl-N-phenyl-N′-tosyl­formamidine

The title compound, C(16)H(18)N(2)O(2)S, was obtained as an unexpected product while attempting to form carbon-nitro-gen bonds by catalytic amidation. The mol-ecule displays an E conformation about the C=N double bond. The planes of the two aromatic rings in the mol-ecule form a dihedral angle of 47.06 (9)°.

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N,N′-[1,3-Phenyl­enebis(methyl­ene)]di-p-toluenesulfonamide

In the title compound, C(22)H(24)N(2)O(4)S(2), the dihedral angles between the central benzene ring and the pendant rings are 66.96 (13) and 69.37 (13)°. The torsion angles for the C-N-S-C fragments are -68.5 (3) and -72.6 (3)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds to generate infinite (001) sheets containing R(4) (4)(28) loops. A weak aromatic π-π stacking contact betw...

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Phenyl N-(p-tol­yl)carbamate

The asymmetric unit of the title compound, C(14)H(13)NO(2), contains two crystallographically independent mol-ecules, in which the aromatic rings are oriented at dihedral angles of 59.01 (3) and 56.98 (3)°. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810011219